By Leslie Tamura
Washington Post Staff Writer
Monday, December 27, 2010; A04
Greenhouse gases other than carbon dioxide may not get as much global attention, but policymakers and business leaders view curbing these emissions as a way that nations can shrink their carbon footprints.
Refrigerators have a role in this story.
For decades, Americans have known only two types of household refrigerators: the pre-1996 fridge that uses an ozone-depleting chlorofluorocarbon (CFC) refrigerant - commonly known by its trademark name, Freon - and the subsequent models that use the global-warming refrigerant called hydrofluorocarbon (HFC).
When CFCs float into the air, their chlorine molecules eat the ozone. HFCs may not harm the ozone, but they can hang in the atmosphere for decades, absorbing radiation that would otherwise be released into space.
A better refrigerant, environmentalists have argued since the early 1990s, is a hydrocarbon refrigerant.
Made of only carbons and hydrogens, these "natural" refrigerants do not degrade the ozone and are easily broken down by the sun. Compared with the atmosphere-degrading refrigerants currently used in American households, hydrocarbons contribute little to global warming.
As early as next year, Americans may have a new hydrocarbon refrigerator option that can reduce their global warming impact and their energy bills. U.S. manufacturers would be entering the HFC-free domestic refrigeration market that the Germans helped establish in 1993.
Back then, the United States was phasing out CFCs, and the chemical industry was introducing HFCs as a possible replacement. Greenpeace, the nonprofit advocacy group, was not happy with the "environmental alternative" to CFCs, said Amy Larkin, director of Greenpeace Solutions.
Although domestic refrigeration accounts for less than 2 percent of current global HFC consumption (automobile air conditioners emit the most HFCs), an HFC refrigerant's impact on the climate is 3,830 times more potent over a 20-year period than the most common greenhouse gas, carbon dioxide.
"But hydrocarbons weren't on anyone's radar," Larkin said, "and when we brought this to the government agencies, telling them these were a better, safe, efficient alternative, we were ridiculed."
Regardless, Greenpeace appealed to a small German manufacturer and helped engineer the world's first hydrocarbon domestic refrigerator. Within three weeks, Greenpeace pre-sold 70,000 HFC-free "Greenfreeze" refrigerators.
Since March 15, 1993, when the first Greenfreeze refrigerator debuted in Germany, more than 400 million hydrocarbon household units have been sold worldwide by several major manufacturers including Whirlpool, Haier and Sanyo.
HFC-free refrigerators have been sold in Mexico, South America, Cuba and parts of Africa, along with Japan, China and throughout Europe.
"Europe has produced incredibly safe, popular refrigerators, but there's still some suspicion in the U.S.," said Durwood Zaelke, director of the Secretariat of the International Network for Environmental Compliance and Enforcement.
Hydrocarbons are flammable, and there have been isolated incidents of exploding hydrocarbon refrigerators.
But manufacturers meet their country's standards and often have an independent safety organization evaluate their appliances. Although hydrocarbon units may have more robust components to prevent leaks, they do not differ much from HFC refrigerators. Typical refrigerators enclose the refrigerant in a hermetically sealed system away from anything that may spark, such as the refrigerator light.
Based on the track record of the hydrocarbon refrigerators, Zaelke said, it's unclear whether concerns about exploding refrigerators is "a true safety concern or just a clever argument for those who make chemicals. One would think they're relatively safe when there are millions sold in Europe."
General Electric plans to introduce the first hydrocarbon household refrigerator in the United States in June 2011, giving Americans a more environmentally friendly option, though at a hefty price.
Insulated with hydrocarbon foam and cooled by a hydrocarbon refrigerant called isobutane, the 30-inch HFC-free refrigerator would be part of GE's luxury Monogram brand, selling for about $6,000 to $6,500.
"You're making a significant investment, but this is all part of the gradual reduction in how much HFCs are used," said Merrell Grant, the general manager of GE Monogram.
Before these refrigerators can roll out to retailers, however, GE says it will wait for final approval from the Environmental Protection Agency's Significant New Alternatives Program.
SNAP, which regulates chemicals or technologies that replace ozone-depleting substances, ruled in 1994 that hydrocarbon refrigerants were too risky to be used in household refrigerators in the United States. According to an EPA spokesman, at the time there was not enough information about the hydrocarbon refrigerant's flammability potential, and there were other non-flammable refrigerants available.
After issuing a proposal in July 2010 to amend the SNAP rule, the EPA is expected to approve use of HFC-free refrigerants in domestic refrigerators next year.
"Hydrocarbons will slowly take over the market," said Stephen O. Andersen, former director of Strategic Climate Projects in the EPA's Climate Protection Partnership Division.
Hydrocarbons are already commonplace in many household appliances - gas stoves, water heaters, furnaces - and used in products such as bathroom cleaners, air fresheners and cooking sprays.
"Refrigerators are safe with hydrocarbons," Andersen said. "Come on, people will hold a blow dryer in one hand, and a can of aerosol hairspray in the other."
A handful of companies based in the United States have started using natural refrigerants in industrial food service equipment. Select Ben & Jerry's stores in Boston and the District received federal approval in 2008 to use hydrocarbon propane freezers as demonstration projects. Coca-Cola has also invested $60 million to advance HFC-free cooling globally.
At the recent United Nations Framework Convention on Climate Change in Cancun, Mexico, 400 international companies, including Unilever and Wal-Mart, pledged they would phase out HFCs from all industrial equipment by 2015. Said former EPA official Andersen: "I think if the market sees the tide changing and starts converting everything to hydrocarbons . . . it could make a big difference."
http://www.washingtonpost.com/wp-dyn/content/article/2010/12/26/AR2010122602479.html